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PTAA

SOL2426

Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine is one of the family members of poly(triaryl)amine.

Polymer for optoelectronic applications.

PTAA can be coated as a substrate material used for hole transport in the manufacture of many devices such as perovskite solar cells, organic light-emitting diodes (OLED) and organic field-effect transistors.

Or buy a specific: PTAA Polyrium batches

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Description

PTAA – SOL2426

CAS: 1333317-99-9

Excellent semiconductor material that transports holes and blocks electrons due to its electron-rich components.

Key Properties of PTAA

  • High charge mobility → Improves the efficiency of hole transport in optoelectronic devices.
  • Excellent thermal and environmental stability → Ideal for demanding applications in solar cells and LEDs.
  • Wide bandgap (~3.0 eV) → Facilitates the use as a hole transport medium with minimal absorption in the visible spectrum.
  • Good solubility in organic solvents → Allows solution processing, reducing manufacturing costs.
  • Compatibility with perovskite layers → Widely used in high-performance perovskite solar cells.

Main Applications

  1. Perovskite solar cells:
    serve as a hole transport layer (HTL), enhancing charge extraction and bolstering the stability of the device.
  2. Organic light-emitting diodes (OLEDs):
    support efficient charge injection and movement in advanced light-emitting systems.
  3. Photodetectors and optical sensors:
    benefit from its robust stability and efficiency, making it suitable for light detection and adaptable electronic uses.
  4. Organic field-effect transistors (OFETs):
    exhibit high charge mobility, positioning them as a superior option for flexible, low-power electronic applications.

Fluoro-PTAA is also available.

 

Choose between:

Low Mw: 5 – 10 kDa (SOL2426L)

Medium Mw: 30 – 75 kDa (SOL2426M)

High Mw: 75 – 200 kDa (SOL2426H)

Ultra-High Mw: 200 – 500 kDa (SOL2426UH)

Custom Mw and pdi available.

 

Safety Data Sheet: SDS-SOL2426

PROMOTIONAL MATERIALSFlyer (English)  | Flyer (English) – ECO

Technical Data Sheet: TDS-SOL2426

Acronyms: PTAA
Chemical Name: Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine]
CAS# 1333317-99-9
Color and Texture: Pale yellow / powder
Molecular Weight: N/A
Absorption, λmax (Media): N/A

 

Emission, λmax (Media): N/A
HOMO (eV): 5.25eV
LUMO (eV): 2.30eV
Decomposition Temperature (°C): 502 °C (under inert atmosphere)
Solubility (Solvent): THF, Toluene, oDCB
Other

 

References:

(1) “Hole-Transport Layer Molecular Weight and Doping Effects on Perovskite Solar Cell Efficiency and Mechanical Behavior

Author(s): Inhwa Lee, Nicholas Rolston, Pierre-Louis Brunner, Reinhold H. Dauskardt*.

Cite this: ACS Appl. Mater. Interfaces 2019, 11, 26, 23757–23764

Publication Date: June 11, 2019

DOI: https://doi.org/10.1021/acsami.9b05567

Copyright © 2019 American Chemical Society

 

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* Price subject to change without prior notice

Products for Research and Development. Laboratory uses only by qualified personnel. The user should read the available SDS and be aware of any precautions to take for the safe manipulation of these materials. Solarischem shall not be held responsible for any damage resulting from the use or handling of these products. Any product can be discontinued, specifications altered or price changed at any time without prior notice. The specifications and structures do not guarantee any product’s suitability for the client’s applications or uses.

 

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